全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药     

时磊  孙艳艳  沈小明  吕爱娟  蔡小虎  刘娇  沈加林 《岩矿测试》2020,39(6):856-865

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS），由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度，在污染物的环境行为研究中得到广泛应用，GC-MS法的定性效果好，但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况，结果显示，即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度，同时保证检测灵敏度，实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法，最终选择中等极性的TG-35MS为第一色谱柱，非极性的（DB-1）为第二色谱柱，将鲜样与无水硫酸钠混合均匀后，以正己烷-丙酮（1：1，V/V）为提取剂进行索氏提取，采用全二维气相色谱-电子捕获检测器进行检测，外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系，相关系数均大于0.995，检出限为0.02~0.17μg/kg。用标准加入法进行回收实验，测得回收率为80.7%~103.5%，测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合，在保证检测灵敏度的同时增加了峰容量，有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式），本方法检出限显著降低，且操作简单，可为复杂基质样品中的痕量超痕量检测提供参考。  相似文献   

小兴安岭-张广才岭铁力地区侏罗纪辉绿岩年代学、地球化学、锆石Hf同位素特征及其构造意义   总被引：1，自引：0，他引：1  

葛茂卉  张进江  刘恺 《岩石学报》2020,36(3):726-740

小兴安岭-张广才岭地区中生代岩浆活动的成因及动力学背景对于揭示古太平洋的构造演化具有重要意义。本文选取小兴安岭-张广才岭铁力地区出露的辉绿岩墙为研究对象,进行锆石LA-ICP-MS U-Pb年代学、全岩地球化学和锆石Hf同位素等分析,对该基性岩的形成时代、岩石成因、岩浆源区以及形成的大地构造背景进行讨论。研究表明:辉绿岩锆石具有高Th/U比值( 0.3),CL图像显示微弱的振荡环带结构,具有岩浆锆石特征,~(206)Pb/~(238)U加权平均年龄为187±2Ma,即形成于早侏罗世;该岩体主要经历了橄榄石和单斜辉石的分离结晶作用,未遭受明显的地壳混染作用,并且具有Rb、Ba、U、Pb、K和Sr等流体活动元素相对富集,Th、Nb和Ta等非流体活动性元素相对亏损的地球化学特征,暗示其形成于被俯冲流体富集交代的亏损地幔部分熔融,源区可能为尖晶石-石榴石二辉橄榄岩,部分熔融程度约为6%～20%。结合该地区同时代的岩浆岩、变形构造、矿床特征和黑龙江蓝片岩的相关报道,本文认为小兴安岭-张广才岭地区在中生代期间处于活动大陆边缘环境,其岩浆岩的形成主要是由于存在于佳木斯地块和松嫩-小兴安岭地块间的牡丹江洋西向俯冲造成的。  相似文献   

Geography Deserts: State and Regional Variation in the Formal Opportunity to Learn Geography in the United States, 2005–2015     

Mark C. Jones  Marcos Luna 《The Journal of geography》2019,118(2):88-100

The formal opportunity to learn geography in the United States is unevenly distributed across space, creating possible geography deserts. Data on the number of exams taken in Advanced Placement Human Geography (APHG) and bachelor’s degrees earned in geography are mapped at the state and regional scales. Normalized rates are ranked and grouped into quintiles. For APHG exams, states in the southeastern region of the United States are in the uppermost quintiles while states in the northeastern region are in the lowermost quintiles. The pattern for bachelor’s degrees in geography is somewhat the spatial inverse of that for APHG.  相似文献   

Spatial patterns and driving mechanisms of mid‐Holocene hydroclimate in western North America          下载免费PDF全文

Nicholas Wayne Hermann  Jessica Leigh Oster  Daniel Enrique Ibarra 《第四纪科学杂志》2018,33(4):421-434

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强夯振动加速度的量测及现场试验研究   总被引：1，自引：0，他引：1       下载免费PDF全文

李盼盼  王家鼎  谷天峰  刘亚明 《地震工程学报》2018,40(1):166-170

结合延安新区强夯加固地基工程,进行强夯振动加速度测试现场试验。选取填方区场地,结合地形设计监测方案,以测试强夯波沿水平方向和斜坡的传播规律。在选定试验段的某级填方场地上布置多组加速度传感器,运用多个8通道24位高速采集卡记录强夯振动加速度在平面和斜坡的传播和衰减过程,探讨强夯振动波沿水平面和斜坡的传播规律以及能级对振动加速度的影响。结果表明:径向和竖向加速度值均随与夯点距离的增大而减小;在与夯击点距离相同处,强夯振动波沿水平方向传播的径向和竖向加速度值要大于沿斜坡方向;随着能级的增大,强夯产生的夯击波增强,在与夯击点相同距离处产生的径向和竖向加速度均明显增大。  相似文献   

A GIS-based multi-proxy analysis of the evolution of subglacial dynamics of the Quebec–Labrador ice dome,northeastern Quebec,Canada     

J.M. Rice  M. Ross  R.C. Paulen  S.E. Kelley  J.P. Briner 《地球表面变化过程与地形》2020,45(13):3155-3177

The glacial records of the inner-core regions of the Laurentide Ice Sheet (LIS) document complex yet coherent patterns reflecting ice-sheet change (e.g. ice-divide migration), providing unique insights into past glacial conditions. This study develops a conceptual model of subglacial dynamics evolution within a major ice-dispersal centre of the LIS in northeastern Quebec, Canada using a GIS-based analysis of the surficial geologic record. Multiple proxies of subglacial conditions (subglacial streamlined landforms, lake density and lake area over thin drift/bedrock) were analysed through grid-overlay techniques and then classified based on different proxy variables ranging from highly mobile warm-based to immobile cold-based conditions. An additional proxy (till blanket) was used to identify areas of thick till deposition, but with few proxies (few lake or landform metrics). Based on local ice-flow reconstructions, the most ‘relict’ glacial terrain zone (GTZ1) has warm-based conditions over 66% of its area and is remarkably well preserved, suggesting laterally extensive warm-based conditions during the oldest identified ice-flow phase. This relict glacial terrain is partially overprinted by two subsequent ice-flow phases in spatially restricted zones in the northeast (73% warm-based), east-central (41% warm-based), and northwest (33% warm-based) of the study area. A zone of more sluggish conditions (only 3% warm-based) was identified in the highlands at the centre of the study area, characterized by thin till cover, few landforms, yet with large patches of relatively abundant small lakes, indicative of areal scouring. No clear evidence of sustained cold-based conditions (i.e. high chemical index of alteration values or high ¹⁰Be abundances) was found in the study area. These results suggest that warm-based conditions (active erosion and/or deposition) were uniformly widespread during the earliest ice-flow phase, later becoming more spatially restricted with broader sluggish ice conditions. These spatially restricted regions of warm-based subglacial regimes were likely controlled by surrounding and down-flow ice streaming. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   

基于高斯烟羽模型的船舶尾气扩散研究     

付金宇  李颖 《海洋通报》2018,(2):235-240

为有效对港区大气污染进行治理、分析船舶尾气,本文详细介绍了一种基于高斯烟羽模型,通过MATLAB模拟仿真模型,其包括实验仿真过程、技术原理及理论模型对船舶尾气扩散进行的研究。该模型是在传统的高斯烟羽模型的基础上,通过对实源像源进行加权选择输入参数;通过矢量合成确定了气体扩散的方向,利用合成后的"风速"进行计算仿真,有效模拟了船舶尾气在港区或者海洋环境中的气体扩散模型。其模型简单且可以有效模拟船舶尾气扩散。并且进一步对后续模型的精确优化进行分析。  相似文献   

内蒙古东部博克图地区石炭纪埃达克质花岗岩地质特征及构造意义     

董洋  刘敬党  刘锦  豆世勇  刘苏  张艳飞  梁帅  杨培奇  梁天意 《地学前缘》2020,27(4):135-149

报道了大兴安岭东部博克图地区二支沟岩体的岩相学、岩石地球化学以及地质年代学特征,探讨了它们的形成时代、岩石成因以及成岩构造背景。根据LA-ICP-MS U-Pb定年结果,二支沟岩体的侵位年龄为(317.2±2.2) Ma与(319.2±2.3) Ma。二支沟岩体岩性为花岗闪长岩,具高硅、富碱,低MgO、CaO的特征,属于准铝质-过铝质,高钾钙碱性I型花岗岩。二支沟岩体的Ba/Nb=70.44~98.20,Ba/La=17.85~28.12,δEu具负异常,暗示源区可能为壳源,存在少量地幔物质与强氧化流体混入。此外,二支沟岩体具有高Sr和低Y、Yb的特征(Sr含量>400×10^-6,Y含量<18×10^-6,Yb含量<1.9×10^-6),与埃达克岩类似,但其更为富钾,表明二支沟岩体具有C型埃达克岩特征。二支沟岩体富集大离子亲石元素(LILE) Rb、K、Ba、Th,相对亏损Ta、Nb、P、Hf、Zr等高强场元素(HFSE),其 (La/Yb)_N=12.05~18.03,轻稀土元素(LREE)富集,重稀土元素(HREE)亏损。其Rb、Ba含量和Rb/Yb(51.49~148.93)、Ba/Yb(430.17~698.83)比值明显高于MORB,与海拉尔盆地和西藏冈底斯埃达克岩相似,表明其成因为底侵作用新生的增厚的玄武质下地壳的熔融。研究区晚石炭世岩浆形成于造山阶段挤压环境。额尔古纳-兴安地块与松嫩地块于晚石炭世((317.2±2.2) Ma之后)构造背景由碰撞造山晚期的挤压、地壳加厚向造山后期的伸展、垮塌的环境转换,并向更加稳定的板内构造环境演变。  相似文献   

河北省怀安县朱家洼矿区地球化学特征与找矿方向     

王占彬 《地质与勘探》2020,56(1):102-112

河北怀安朱家洼矿区位于华北板块北缘中段太古宙、元古宙、中生代金银铅锌铁硫铁矿成矿带,为火山热液型金多金属矿。为查明该区成矿规律,明确找矿方向,在区内开展了水系沉积物测量、土壤地球化学测量等工作。通过对元素分布、元素相关性、元素异常等特征研究表明,Au、Mo为本区主成矿元素;各元素异常平面分布具有分带性,高温元素W、Sn、Bi异常位于骆驼山火山机构中心,中低温元素Pb、Zn、As、Ag等异常分布于火山机构边部及周边围岩中,成矿元素Au、Mo异常主要位于火山机构西侧围岩中。异常查证发现金钼矿化体2条,金钼矿化受火山机构和北西向构造带控制。依据成矿地质条件、地球化学异常及查证成果认为,朱家洼矿区Au、Mo成矿潜力大,火山机构西侧围岩区是该区重点找矿地段。  相似文献   

Long‐term streamflow trends in Hawai'i and implications for native stream fauna     

Hannah M. Clilverd  Yin‐Phan Tsang  Dana M. Infante  Abigail J. Lynch  Ayron M. Strauch 《水文研究》2019,33(5):699-719

Climate change has fundamentally altered the water cycle in tropical islands, which is a critical driver of freshwater ecosystems. To examine how changes in streamflow regime have impacted habitat quality for native migratory aquatic species, we present a 50‐year (1967–2016) analysis of hydrologic records in 23 unregulated streams across the five largest Hawaiian Islands. For each stream, flow was separated into direct run‐off and baseflow and high‐ and low‐flow statistics (i.e., Q10 and Q90) with ecologically important hydrologic indices (e.g., frequency of flooding and low flow duration) derived. Using Mann–Kendall tests with a running trend analysis, we determined the persistence of streamflow trends through time. We analysed native stream fauna from ~400 sites, sampled from 1992 to 2007, to assess species richness among islands and streams. Declines in streamflow metrics indicated a general drying across the islands. In particular, significant declines in low flow conditions (baseflows), were experienced in 57% of streams, compared with a significant decline in storm flow conditions for 22% of streams. The running trend analysis indicated that many of the significant downward trends were not persistent through time but were only significant if recent decades (1987–2016) were included, with an average decline in baseflow and run‐off of 10.90% and 8.28% per decade, respectively. Streams that supported higher native species diversity were associated with moderate discharge and baseflow index, short duration of low flows, and negligible downward trends in flow. A significant decline in dry season flows (May–October) has led to an increase in the number of no‐flow days in drier areas, indicating that more streams may become intermittent, which has important implications for mauka to makai (mountain to ocean) hydrological connectivity and management of Hawai'i's native migratory freshwater fauna.  相似文献